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dmso in organic chemistry: Solvents as Reagents in Organic Synthesis Xiao-Feng Wu, 2018-01-03 Written by highly renowned and experienced authors, this is the only reference on the application of solvents as reagents. Clearly structured, the text describes various methods for the activation and reaction of these small molecules, highlighting the synthetic opportunities as well as process-oriented advantages. To this end, all relevant types of solvents are covered separately and emphasized with numerous synthetic examples, while taking care to explain applications so as to avoid undesired side reactions. The result is a unique resource for every synthetic chemist and reaction engineer in industry and academia working on the methodical optimization of synthetic transformations. |
dmso in organic chemistry: Advanced Organic Chemistry Francis A. Carey, Richard J. Sundberg, 2006-05-02 The control of reactivity to achieve specific syntheses is one of the overarching goals of organic chemistry. In the decade since the publication of the third edition, major advances have been made in the development of efficient new methods, particularly catalytic processes, and in means for control of reaction stereochemistry. This volume assumes a level of familiarity with structural and mechanistic concepts comparable to that in the companion volume, Part A, Structures and Mechanisms. Together, the two volumes are intended to provide the advanced undergraduate or beginning graduate student in chemistry with a sufficient foundation to comprehend and use the research literature in organic chemistry. The New Revised 5th Edition will be available shortly. For details, click on the link in the right-hand column. |
dmso in organic chemistry: Oxidation of Alcohols to Aldehydes and Ketones Gabriel Tojo, Marcos I. Fernandez, 2006-06-15 The aim of this book is to help people performing routine operations in Organic Synthesis in a laboratory. This book, the first one in a series, focuses on the oxidation of alcohols to aldehydes and ketones. Probably, this is the most important routine operation in Organic Synthesis. |
dmso in organic chemistry: Handbook of Solvents George Wypych, 2001 A comprehensive, extensive textual analysis of the principles of solvent selection and use, the handbook is intended to help formulators select ideal solvents, safety coordinators to protect workers, and legislators and inspectors to define and implement technically correct public safeguards for use, handling, and disposal. |
dmso in organic chemistry: Comprehensive Organic Chemistry Experiments for the Laboratory Classroom Carlos A. M. Afonso, Nuno R. Candeias, Dulce Pereira Simão, Alexandre F. Trindade, Jaime A. S. Coelho, Bin Tan, Robert Franzén, 2016-12-16 This expansive and practical textbook contains organic chemistry experiments for teaching in the laboratory at the undergraduate level covering a range of functional group transformations and key organic reactions.The editorial team have collected contributions from around the world and standardized them for publication. Each experiment will explore a modern chemistry scenario, such as: sustainable chemistry; application in the pharmaceutical industry; catalysis and material sciences, to name a few. All the experiments will be complemented with a set of questions to challenge the students and a section for the instructors, concerning the results obtained and advice on getting the best outcome from the experiment. A section covering practical aspects with tips and advice for the instructors, together with the results obtained in the laboratory by students, has been compiled for each experiment. Targeted at professors and lecturers in chemistry, this useful text will provide up to date experiments putting the science into context for the students. |
dmso in organic chemistry: Separation Methods in Drug Synthesis and Purification Klara Valko, 2000-10-13 Separation Methods in Drug Synthesis and Purification |
dmso in organic chemistry: Tables of Spectral Data for Structure Determination of Organic Compounds Ernö Pretsch, T. Clerc, J. Seibl, W. Simon, 2013-06-29 Although numerical data are, in principle, universal, the compilations presented in this book are extensively annotated and interleaved with text. This translation of the second German edition has been prepared to facilitate the use of this work, with all its valuable detail, by the large community of English-speaking scientists. Translation has also provided an opportunity to correct and revise the text, and to update the nomenclature. Fortunately, spectroscopic data and their relationship with structure do not change much with time so one can predict that this book will, for a long period of time, continue to be very useful to organic chemists involved in the identification of organic compounds or the elucidation of their structure. Klaus Biemann Cambridge, MA, April 1983 Preface to the First German Edition Making use of the information provided by various spectroscopic tech niques has become a matter of routine for the analytically oriented organic chemist. Those who have graduated recently received extensive training in these techniques as part of the curriculum while their older colleagues learned to use these methods by necessity. One can, therefore, assume that chemists are well versed in the proper choice of the methods suitable for the solution of a particular problem and to translate the experimental data into structural information. |
dmso in organic chemistry: Dimethyl Sulfoxide (DMSO) in Trauma and Disease Stanley W. Jacob, Jack C. de la Torre, 2015-04-07 First isolated as a chemical compound by a Russian chemist in 1866, dimethyl sulfoxide (DMSO) proved to be a near-perfect solvent for decades before its remarkable biological and medical activities were discovered. DMSO is one of the most prodigious agents ever to come out of the world of drug development. Its wide range of biological actions invol |
dmso in organic chemistry: Green Solvents in Organic Synthesis Xiao-Feng Wu, Zhiping Yin, Liang-nian He, Feng Wang, 2024-03-11 Green Solvents in Organic Synthesis Essential reference on replacing conventional solvents with greener alternatives in industrial chemicals synthesis and production A well-timed book promoting sustainability in synthesis and production of chemicals, Green Solvents in Organic Synthesis details various green solvents, solvent systems, and solubilization techniques, including their chemistry, physiochemical properties, performance, and distinct applications, presenting a greener approach to conventional solvents by replacing them with sustainable alternatives that have similarities in their reaction mechanisms. Edited by four highly qualified academics with significant research experience in the field, Green Solvents in Organic Synthesis includes information on: Water and liquid polymers (Polyethylene glycol PEG), Acetonitrile, DMSO, Dimethyl carbonate, Ionic liquids, and Supercritical fluids) Bio-based solvents (Cyrene, γ-Valerolactone (GVL), Lactic acid, 2-MeTHF) and deep eutectic solvents (DESs) Alcohols (MeOH, EtOH, i-PrOH, n-BuOH, t-BuOH, Ethylene glycol), ketones (Acetones, MEK, MIBK, Cyclohexanone), and esters (Methyl acetate, Ethyl acetate, i-PrOAc, n-BuOAc) Technical, economic, and environmental aspects of green solvents and how to maximize their reuse and recycling to alleviate pollution and reduce energy consumption For chemists in a variety of disciplines, Green Solvents in Organic Synthesis is an essential reference that provides foundational knowledge of green solvents, along with key features of each class of green solvent within the context of organic reactions for industrial and laboratory synthesis. |
dmso in organic chemistry: Introduction to Strategies for Organic Synthesis Laurie S. Starkey, 2012-01-18 The stepping-stone text for students with a preliminary knowledge of organic chemistry looking to move into organic synthesis research and graduate-level coursework Organic synthesis is an advanced but important field of organic chemistry, however resources for advanced undergraduates and graduate students moving from introductory organic chemistry courses to organic synthesis research are scarce. Introduction to Strategies for Organic Synthesis is designed to fill this void, teaching practical skills for making logical retrosynthetic disconnections, while reviewing basic organic transformations, reactions, and reactivities. Divided into seven parts that include sections on Retrosynthesis and Protective Groups; Overview of Organic Transformations; Synthesis of Monofunctional Target Molecules; Synthesis of Target Molecules with Two Functional Groups; Synthesis of Aromatic Target Molecules; Synthesis of Compounds Containing Rings; and Predicting and Controlling Stereochemistry, the book covers everything students need to successfully perform retrosynthetic analyses of target molecule synthesis. Starting with a review of functional group transformations, reagents, and reaction mechanisms, the book demonstrates how to plan a synthesis, explaining functional group analysis and strategic disconnections. Incorporating a review of the organic reactions covered, it also demonstrates each reaction from a synthetic chemist's point of view, to provide students with a clearer understanding of how retrosynthetic disconnections are made. Including detailed solutions to over 300 problems, worked-through examples and end-of-chapter comprehension problems, Introduction to Strategies for Organic Synthesis serves as a stepping stone for students with an introductory knowledge of organic chemistry looking to progress to more advanced synthetic concepts and methodologies. |
dmso in organic chemistry: Organic Chemistry David R. Klein, 2022 Organic Chemistry, 4th Edition provides a comprehensive, yet accessible treatment of all the essential organic chemistry concepts covered in a two-semester course. Presented with a skills-based approach that bridges the gap between organic chemistry theory and real-world practice, the book places special emphasis on developing their problem-solving skills through applied exercises and activities. It incorporates Klein's acclaimed SkillBuilder program which contains a solved problem that demonstrates a skill and several practice problems of varying difficulty levels�including conceptual and cumulative problems that challenge students to apply the skill in a slightly different environment. An up-to-date collection of literature-based problems exposes students to the dynamic and evolving nature of organic chemistry and its active role in addressing global challenges. The text is also enriched with numerous hands-on activities and real-world examples that help students understand both the why and the how behind organic chemistry. |
dmso in organic chemistry: Writing Reaction Mechanisms in Organic Chemistry Audrey Miller, Philippa H. Solomon, 2012-12-02 Presentation is clear and instructive: students will learn to recognize that many of the reactions in organic chemistry are closely related and not independent facts needing unrelated memorization. The book emphasizes that derivation of a mechanism is not a theoretical procedure, but a means of applying knowledge of other similar reactions and reaction conditions to the new reaction. - Brief summaries of required basic knowledge of organic structure, bonding, stereochemistry, resonance, tautomerism, and molecular orbital theory - Definitions of essential terms - Typing and classification of reactions - Hints (rules) for deriving the most likely mechanism for any reaction |
dmso in organic chemistry: Pinch Me If You Can My Unique Books, 2019-08-02 Get prepared for the upcoming school year and get organized with this notepad. A great place to record the main important information of your class, lecture or meeting and to create a to-do list. PICK THIS PRODUCT NOW! Perfect for girls or boys, this notebook can also be used as a diary. Features: ample room for notes on lined journal pages. Product description: 5 x 8; 120 pages of lined paper, uniquely designed matte cover. We have lots of great notebooks, sheet music, planners and journals, so be sure to check out our other listings by clicking on the Author Name link just below the title of this tracker. Ideas on how to use this journal: back to school shopping; high school student gift; middle school student present; teacher supplies for university and college; pupils who like sketching and doodling. |
dmso in organic chemistry: Infrared and Raman Spectroscopy Peter Larkin, 2017-11-13 Infrared and Raman Spectroscopy, Principles and Spectral Interpretation, Second Edition provides a solid introduction to vibrational spectroscopy with an emphasis on developing critical interpretation skills. This book fully integrates the use of both IR and Raman spectroscopy as spectral interpretation tools, enabling the user to utilize the strength of both techniques while also recognizing their weaknesses. This second edition more than doubles the amount of interpreted IR and Raman spectra standards and spectral unknowns. The chapter on characteristic group frequencies is expanded to include increased discussions of sulphur and phosphorus organics, aromatic and heteroaromatics as well as inorganic compounds. New topics include a discussion of crystal lattice vibrations (low frequency/THz), confocal Raman microscopy, spatial resolution in IR and Raman microscopy, as well as criteria for selecting Raman excitation wavelengths. These additions accommodate the growing use of vibrational spectroscopy for process analytical monitoring, nanomaterial investigations, and structural and identity determinations to an increasing user base in both industry and academia. - Integrates discussion of IR and Raman spectra - Pairs generalized IR and Raman spectra of functional groups with tables and text - Includes over 150 fully interpreted, high quality IR and Raman reference spectra - Contains fifty-four unknown IR and Raman spectra, with a corresponding answer key |
dmso in organic chemistry: Handbook of Odors in Plastic Materials George Wypych, 2023-02-07 Handbook of Odors in Plastic Materials, Third Edition analyzes the reasons behind unwanted odor formation and outlines methods for prevention. This new edition contains a thorough review of the most recent data, achievements and information in this less known but very significant field of polymer modification. The book covers the fundamentals of odor formation and its transport within a material, the relationship between odor and toxicity, and various methods of odor removal and unwanted odor formation. Three chapters are devoted to the analysis of odor-related matters in different polymers, products and methods of processing. Dozens of polymers and product groups are analyzed, and the book also discusses regulations related to odor in products, effects of odor on health and safety, the effect of odors from plastic materials on indoor air quality, information on testing of odor changes, as well as a selection of raw materials for fog-free products. - Analyzes the reasons behind odor formation - Provides the best methods to prevent odors in various plastic materials - Contains information on testing odor changes and the relationship between odor and toxicity - Includes a comprehensive list of methods for removal of unwanted odors from plastic materials |
dmso in organic chemistry: Oxidation in Organic Synthesis V. K. Ahluwalia, 2012-02-13 Oxidation plays a crucial role in organic synthesis. This volume presents the array of oxidizing agents and their applications in oxidations. The book describes in great detail a number of reagents of importance. The text includes oxidation of specific types of organic compounds including hydrocarbons, alcohols, phenols, ethers, carbonyl compounds, carboxylic acids, amides, hydrazides, nitro compounds, nitroso compounds, hydroxylamines, azo compounds, azides, hydrazo compounds, amines, phosphorus, arsenic and sulphur compounds. It also covers enzymatic or microbial oxidations as well as oxidations under benign conditions. |
dmso in organic chemistry: Essential Practical NMR for Organic Chemistry S. A. Richards, J. C. Hollerton, 2022-12-22 Essential Practical NMR for Organic Chemistry A hands-on resource advocating an ordered approach to gathering and interpreting NMR data The second edition of Essential Practical NMR for Organic Chemistry delivers a pragmatic and accessible text demonstrating an ordered approach to gathering and interpreting NMR data. In this informal guide, you’ll learn to make sense of the high density of NMR information through the authors’ problem-solving strategies and interpretations. The book also discusses critical aspects of NMR theory, as well as data acquisition and processing strategy. It explains the use of NMR spectroscopy for dealing with problems of small organic molecule structural elucidation and includes a brand-new chapter on Nitrogen-15 NMR. Readers will also find: Strategies for preparing a sample, spectrum acquisition, processing, and interpreting your spectrum Fulsome discussions of Carbon-13 NMR spectroscopy Practical treatments of quantification, safety procedures, and relevant software An ideal handbook for anyone involved in using NMR to solve structural problems, this latest edition of Essential Practical NMR for Organic Chemistry will be particularly useful for chemists running and looking at their own NMR spectra, as well as those who work in small molecule NMR. It will also earn a place in the libraries of undergraduate and post-graduate organic chemistry students. |
dmso in organic chemistry: Sustainable Organic Synthesis Dr Stefano Protti, Professor Alessandro Palmieri, 2021-10-29 Recent years have seen huge growth in the area of sustainable chemistry. In order to meet the chemical needs of the global population whilst minimising impacts on health and the environment it is essential to keep reconsidering and improving synthetic processes. Sustainable Organic Synthesis is a comprehensive collection of contributions, provided by specialists in Green Chemistry, covering topics ranging from catalytic approaches to benign and alternative reaction media, and innovative and more efficient technologies. |
dmso in organic chemistry: Aromatic Thiols and Their Derivatives Ismayil A. Aliyev, Boris A. Trofimov, Lyudmila A. Oparina, 2021-05-24 This book is devoted to the synthetic and physical chemistry of aromatic thiols and their closest derivatives, sulfides, sulfoxides, sulfones, including those substituted by various functional groups such as acyl and thioacyl, alkoxide, ester, hydroxyl and halogens. In some cases, for comparison, selenium and oxygen analogues are also detailed. The main focus of the book is on synthetic methods, both traditional and new, based on the use of transition metals as catalysts, as well as the reactivity of the compounds obtained. Its addition to the influence of conformational and electronic factors on spectral (NMR, IR, UV, NQR) and electrochemical characteristics of the compounds is presented. Finally, the book describes the application of aromatic thiols and their derivatives as drug precursors, high-tech materials, building blocks for organic synthesis, analytical reagents and additives for oils and fuels. It is a useful handbook for all those interested in organosulfur chemistry. |
dmso in organic chemistry: Comprehensive Organic Synthesis , 2014-02-14 The second edition of Comprehensive Organic Synthesis—winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers—builds upon the highly respected first edition in drawing together the new common themes that underlie the many disparate areas of organic chemistry. These themes support effective and efficient synthetic strategies, thus providing a comprehensive overview of this important discipline. Fully revised and updated, this new set forms an essential reference work for all those seeking information on the solution of synthetic problems, whether they are experienced practitioners or chemists whose major interests lie outside organic synthesis. In addition, synthetic chemists requiring the essential facts in new areas, as well as students completely new to the field, will find Comprehensive Organic Synthesis, Second Edition, Nine Volume Set an invaluable source, providing an authoritative overview of core concepts. Winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers Contains more than170 articles across nine volumes, including detailed analysis of core topics such as bonds, oxidation, and reduction Includes more than10,000 schemes and images Fully revised and updated; important growth areas—including combinatorial chemistry, new technological, industrial, and green chemistry developments—are covered extensively |
dmso in organic chemistry: Beilsteins Handbuch Der Organischen Chemie Friedrich Konrad Beilstein, Bernhard Prager, Paul Jacobson, 2015-09-27 This work has been selected by scholars as being culturally important, and is part of the knowledge base of civilization as we know it. This work was reproduced from the original artifact, and remains as true to the original work as possible. Therefore, you will see the original copyright references, library stamps (as most of these works have been housed in our most important libraries around the world), and other notations in the work.This work is in the public domain in the United States of America, and possibly other nations. Within the United States, you may freely copy and distribute this work, as no entity (individual or corporate) has a copyright on the body of the work.As a reproduction of a historical artifact, this work may contain missing or blurred pages, poor pictures, errant marks, etc. Scholars believe, and we concur, that this work is important enough to be preserved, reproduced, and made generally available to the public. We appreciate your support of the preservation process, and thank you for being an important part of keeping this knowledge alive and relevant. |
dmso in organic chemistry: Principles of Chemical Nomenclature G. J. Leigh, 2011 Aimed at pre-university and undergraduate students, this volume surveys the current IUPAC nomenclature recommendations in organic, inorganic and macromolecular chemistry. |
dmso in organic chemistry: The Art of Problem Solving in Organic Chemistry Miguel E. Alonso-Amelot, 2023-09-06 The new edition of the classic textbook that has helped thousands of students understand and solve the complex mechanistic problems posed by organic reactions The Art of Problem Solving in Organic Chemistry is a must-have handbook for students and professionals alike, offering step-by-step guidance on applying proven strategies and logical techniques to solve complex reaction mechanism problems. With a straightforward approach and conversational style, this highly practical resource provides fully worked organic reaction problems that increase in difficulty from basic to advanced. Organized by specific analysis technique, the problems include complete and accurate discussions of the mechanisms, alternative pathways, comparisons with related reactions, data from quantum chemical calculations, critical reviews of current methods, real-world research and reaction schemes, and illustrated examples. Now in its third edition, The Art of Problem Solving in Organic Chemistry retains the structure of previous editions, previously rated among the 30 best organic chemistry books of all time by BookAuthority. More than 50 revised organic reaction mechanism problems are complemented by an entirely new set of problems, additional concepts and techniques, expanded coverage of applications in contemporary organic chemistry, embedded cases of the existing reaction pool taken from recent literature, and much more. Describes the principles, methods, tools, and problem analysis techniques required to solve organic reaction problems Extends the logic and strategy of the mechanistic approach beyond specific reactions and facts Discusses practical methods for improved problem solving for organic reaction mechanisms Explains tested strategies for analyzing the possibilities of reaction mechanisms between reactants and products Contains detailed appendices with definitions and examples of principles, reactions, mechanisms, and reagents The Art of Problem Solving in Organic Chemistry, Third Edition is an essential volume for advanced undergraduates, graduate students, lecturers, and professionals looking to improve their performance in finding solutions to organic reaction problems. It is an ideal textbook for courses on organic reactions and problem analysis, as well as an excellent supplement for courses covering reactive intermediates and mechanisms of molecular transformations. |
dmso in organic chemistry: Practical Synthetic Organic Chemistry Stéphane Caron, 2011-07-26 A hands-on guide to assist in the planning and execution of synthetic reactions in the laboratory Despite the maturity of organic chemistry, it can still be very challenging to identify optimal methods for synthetic transformations that perform as well in real-world manufacturing processes as they do in the laboratory. This detailed and accessible guide attempts to address this vexing issue and deliver proven methodologies practicing synthetic chemists will find valuable for identifying reaction conditions that work reliably over the broadest possible range of substrates. Practical Synthetic Organic Chemistry: Provides a practical guide to strategically planning and executing chemical syntheses for the bench chemist in industry Discusses information that is not common knowledge beyond the boundaries of process chemistry groups, such as the synthetic routes of selected contemporary pharmaceutical drugs and practical solvents, as well as green chemistry concepts Highlights key reactions, including substitutions, additions, eliminations, rearrangements, oxidations, and reductions Addresses basic principles, mechanisms, advantages and disadvantages of the methodology, and techniques for achieving laboratory success Incorporating such an extraordinary wealth of information on organic chemistry and its related fields into one complete volume distinguishes Practical Synthetic Organic Chemistry as an incomparable desktop reference for professionals and an invaluable study aid for students. |
dmso in organic chemistry: Pharmacology and Applications of Naturally Occurring Iridoids Biswanath Dinda, 2019-03-26 In this book, the author provides expert analysis on naturally occurring iridoids, their chemistry and their distribution in plants and insects. Particular attention is given to the pharmacology of iridoids and their prospective applications in pharmaceutical and agricultural industries. Iridoids are found in a wide variety of plants and some insects, and they are structurally derived from monoterpenoid natural products. In the first two chapters of this book, the author describes the iridoids classification, occurrence and distribution in plants and insects. The following chapters cover different chromatographic and spectroscopic techniques that can be used to identify and quantify iridoids in herbal formulations, and also the biosynthesis of iridoids, in which the reader will discover a metabolomics and transcriptomics analysis to identify the genes involved in the biosynthesis. The final chapters provide insights on several pharmacological activities of iridoids, their physiological role in insects, pharmacokinetics in mammals, insects and microorganisms, and their applications in medicine and agriculture. This book will engage students and researchers interested in the chemistry of natural products, and it will also appeal to medicinal chemists and practitioners working in the design of new herbal drugs with bioactive pure iridoids. |
dmso in organic chemistry: Cryopreservation and Freeze-Drying Protocols John G. Day, Glyn Stacey, 2007-06-05 In addition to outlining the fundamental principles associated with the conservation of biological resources, freeze-drying and cryopreservation, this text is a compilation of cryptopreservation and freeze-drying methodologies applicable to different biological materiels, developed by expert laboratories. |
dmso in organic chemistry: Advances in Physical Organic Chemistry , 1989-06-05 This series, established by Victor Gold in 1963, brings before the chemical community substantial, authoritative, and considered reviews of areas of chemistry in which quantitative methods are used in the study of the structures of organic compounds and their relation to physical and chemical properties.Physical organic chemistry is viewed as a particular approach to scientific enquiry rather than a further intellectual specialization. Organometallic compounds are included, and relevant aspects of physical theoretical, inorganic, and biological chemistry are incorporated in reviews where appropriate. |
dmso in organic chemistry: Electronic Effects in Organic Chemistry Barbara Kirchner, 2014-10-27 The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. Review articles for the individual volumes are invited by the volume editors. Readership: research chemists at universities or in industry, graduate students |
dmso in organic chemistry: Bio-Based Solvents François Jérôme, Rafael Luque, 2017-06-29 A multidisciplinary overview of bio-derived solvent applications, life cycle analysis, and strategies required for industrial commercialization This book provides the first and only comprehensive review of the state-of-the-science in bio-derived solvents. Drawing on their own pioneering work in the field, as well as an exhaustive survey of the world literature on the subject, the authors cover all the bases—from bio-derived solvent applications to life cycle analysis to strategies for industrial commercialization—for researchers and professional chemists working across a range of industries. In the increasingly critical area of sustainable chemistry, the search for new and better green solvents has become a top priority. Thanks to their renewability, biodegradability and low toxicity, as well as their potential to promote advantageous organic reactions, green solvents offer the promise of significantly reducing the pernicious effects of chemical processes on human health and the environment. Following an overview of the current solvents markets and the challenges and opportunities presented by bio-derived solvents, a series of dedicated chapters cover all significant classes of solvent arranged by origin and/or chemical structure. Throughout, real-world examples are used to help demonstrate the various advantages, drawbacks, and limitations of each class of solvent. Topics covered include: The commercial potential of various renewably sourced solvents, such as glycerol The various advantages and disadvantages of bio-derived versus petroleum-based solvents Renewably-sourced and waste-derived solvents in the design of eco-efficient processes Life cycle assessment and predictive methods for bio-based solvents Industrial and commercial viability of bio-based solvents now and in the years ahead Potential and limitations of methodologies involving bio-derived solvents New developments and emerging trends in the field and the shape of things to come Considering the vast potential for new and better products suggested by recent developments in this exciting field, Bio-Based Solvents will be a welcome resource among students and researchers in catalysis, organic synthesis, electrochemistry, and pharmaceuticals, as well as industrial chemists involved in manufacturing processes and formulation, and policy makers. |
dmso in organic chemistry: Superbases for Organic Synthesis Tsutomu Ishikawa, 2009-01-26 Guanidines, amidines and phosphazenes have been attracting attention in organic synthesis due to their potential functionality resulting from their extremely strong basicity. They are also promising catalysts because of their potential for easy molecular modification, possible recyclability, and reduced or zero toxicity. Importantly, these molecules can be derived as natural products – valuable as scientists move towards “sustainable chemistry”, where reagents and catalysts are derived from biomaterial sources. Superbases for Organic Synthesis is an essential guide to these important molecules for preparative organic synthesis. Topics covered include the following aspects: an introduction to organosuperbases physicochemical properties of organic superbases amidines and guanidines in organic synthesis phosphazene: preparation, reaction and catalytic role polymer-supported organosuperbases application of organosuperbases to total synthesis related organocatalysts: proton sponges and urea derivatives amidines and guanidines in natural products and medicines Superbases for Organic Synthesis is a comprehensive, authoritative and up-to-date guide to these important reagents for organic chemists, drug discovery researchers and those interested in the chemistry of natural products. |
dmso in organic chemistry: Mechanochemical Organic Synthesis Davor Margetic, Vjekoslav Štrukil, 2016-04-23 Mechanochemical Organic Synthesis is a comprehensive reference that not only synthesizes the current literature but also offers practical protocols that industrial and academic scientists can immediately put to use in their daily work. Increasing interest in green chemistry has led to the development of numerous environmentally-friendly methodologies for the synthesis of organic molecules of interest. Amongst the green methodologies drawing attention, mechanochemistry is emerging as a promising method to circumvent the use of toxic solvents and reagents as well as to increase energy efficiency. The development of synthetic strategies that require less, or the minimal, amount of energy to carry out a specific reaction with optimum productivity is of vital importance for large-scale industrial production. Experimental procedures at room temperature are the mildest reaction conditions (essentially required for many temperature-sensitive organic substrates as a key step in multi-step sequence reactions) and are the core of mechanochemical organic synthesis. This green synthetic method is now emerging in a very progressive manner and until now, there is no book that reviews the recent developments in this area. - Features cutting-edge research in the field of mechanochemical organic synthesis for more sustainable reactions - Integrates advances in green chemistry research into industrial applications and process development - Focuses on designing techniques in organic synthesis directed toward mild reaction conditions - Includes global coverage of mechanochemical synthetic protocols for the generation of organic compounds |
dmso in organic chemistry: Modelling 1H NMR Spectra of Organic Compounds Raymond J. Abraham, Mehdi Mobli, 2008-11-20 Provides a theoretical introduction to graduate scientists and industrial researchers towards the understanding of the assignment of 1H NMR spectra Discusses, and includes on enclosed CD, one of the best, the fastest and most applicable pieces of NMR prediction software available Allows students of organic chemistry to solve problems on 1H NMR with access to over 500 assigned spectra |
dmso in organic chemistry: Coordination Chemistry in Non-Aqueous Solutions Victor Gutmann, 2012-12-06 Considerable attention has been focussed on non-aqueous chemistry in the last decade and this situation has arisen no doubt from a realization of the vast application of this branch of chemistry. Within this field much energetic work has been channelled into the determination of the coordination chemistry of tran sition metals in these solvent 8ystems. Elaborate experimental techniques have been developed to discover, in particular, the magnetic and spectral properties of complex compounds, and the theoretical background of such systems has been expanded to corroborate, as far as possible, the experimental results. This text has, however, a different bias from many books currently available on this branch of chemistry, and is designed to be a survey of known facts on many of the non-aqueous solvents currently in use mainly in the field of halogen chemistry, together with a discussion of these facts in the light of accepted principles. As such, it is hoped to close a gap in the literature of which many workers and advanced students in this field will be aware. The treatment is meant to be selective rather than completely comprehensive and must unevitably reflect some of the special interests of the author. |
dmso in organic chemistry: March's Advanced Organic Chemistry Michael B. Smith, Jerry March, 2007-01-29 The Sixth Edition of a classic in organic chemistry continues its tradition of excellence Now in its sixth edition, March's Advanced Organic Chemistry remains the gold standard in organic chemistry. Throughout its six editions, students and chemists from around the world have relied on it as an essential resource for planning and executing synthetic reactions. The Sixth Edition brings the text completely current with the most recent organic reactions. In addition, the references have been updated to enable readers to find the latest primary and review literature with ease. New features include: More than 25,000 references to the literature to facilitate further research Revised mechanisms, where required, that explain concepts in clear modern terms Revisions and updates to each chapter to bring them all fully up to date with the latest reactions and discoveries A revised Appendix B to facilitate correlating chapter sections with synthetic transformations |
dmso in organic chemistry: Current Organic Chemistry , 1999-03 |
dmso in organic chemistry: Advanced Organic Chemistry Reinhard Bruckner, 2002 A best-selling mechanistic organic chemistry text in Germany, this text's translation into English fills a long-existing need for a modern, thorough and accessible treatment of reaction mechanisms for students of organic chemistry at the advanced undergraduate and graduate level. Knowledge of reaction mechanisms is essential to all applied areas of organic chemistry; this text fulfills that need by presenting the right material at the right level. |
dmso in organic chemistry: Dmso Morton Walker D.P.M., 1993-01-01 An easy-to-understand, up-to-date guide on the highly publicized drug, DMSO DMSO—dimethyl sulfoxide—is a simple by-product of wood and has been called a “miracle” drug, capable of relieving pain, diminishing swelling, reducing inflammation, encouraging healing, and restoring normal function. In this groundbreaking work, award-winning health science writer Dr. Morton Walker examines the powerful and compelling case for the use of DMSO in the treatment of many debilitating disease and health-related problems. In DMSO: Nature’s Healer, Dr. Walker cites documented cases of its astounding use in healing and prevention of a host of health disorders, including arthritis, stroke, cancer, mental retardation, and sports and auto injuries. He also recounts the dramatic story of the long struggle to gain FDA approval of DMSO. |
dmso in organic chemistry: March's Advanced Organic Chemistry Michael B. Smith, 2019-12-11 The completely revised and updated, definitive resource for students and professionals in organic chemistry The revised and updated 8th edition of March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure explains the theories of organic chemistry with examples and reactions. This book is the most comprehensive resource about organic chemistry available. Readers are guided on the planning and execution of multi-step synthetic reactions, with detailed descriptions of all the reactions The opening chapters of March's Advanced Organic Chemistry, 8th Edition deal with the structure of organic compounds and discuss important organic chemistry bonds, fundamental principles of conformation, and stereochemistry of organic molecules, and reactive intermediates in organic chemistry. Further coverage concerns general principles of mechanism in organic chemistry, including acids and bases, photochemistry, sonochemistry and microwave irradiation. The relationship between structure and reactivity is also covered. The final chapters cover the nature and scope of organic reactions and their mechanisms. This edition: Provides revised examples and citations that reflect advances in areas of organic chemistry published between 2011 and 2017 Includes appendices on the literature of organic chemistry and the classification of reactions according to the compounds prepared Instructs the reader on preparing and conducting multi-step synthetic reactions, and provides complete descriptions of each reaction The 8th edition of March's Advanced Organic Chemistry proves once again that it is a must-have desktop reference and textbook for every student and professional working in organic chemistry or related fields. Winner of the Textbook & Acadmic Authors Association 2021 McGuffey Longevity Award. |
dmso in organic chemistry: Strategic Applications of Named Reactions in Organic Synthesis Laszlo Kurti, Barbara Czako, 2005-04-29 Kurti and Czako have produced an indispensable tool for specialists and non-specialists in organic chemistry. This innovative reference work includes 250 organic reactions and their strategic use in the synthesis of complex natural and unnatural products. Reactions are thoroughly discussed in a convenient, two-page layout--using full color. Its comprehensive coverage, superb organization, quality of presentation, and wealth of references, make this a necessity for every organic chemist. - The first reference work on named reactions to present colored schemes for easier understanding - 250 frequently used named reactions are presented in a convenient two-page layout with numerous examples - An opening list of abbreviations includes both structures and chemical names - Contains more than 10,000 references grouped by seminal papers, reviews, modifications, and theoretical works - Appendices list reactions in order of discovery, group by contemporary usage, and provide additional study tools - Extensive index quickly locates information using words found in text and drawings |
dmso in organic chemistry: Physical Organic Chemistry — 3 A. Fruchier, 2017-09-29 9780080211978 Physical Organic Chemistry - 3 (Montpellier, 1976) is a collection of plenary lectures presented at the Third IUPAC Conference on Physical Organic Chemistry, held in Montpellier, France on September 6-10, 1976. This book is composed of nine chapters and begins with an examination of the concept of absolute equilibrium acidity scale and its application to structure-activity relationship evaluation. The succeeding chapters deal with micellar catalysis and inhibition, as well as the application of quantum chemical ab initio methods to CO, CS, and related double bonds. These topics are followed by discussions of the hydrolysis of acetals and hemiacetals; the mechanisms and catalysis in vinyl ester hydrolysis; and the acid-base catalysis of carbonyl and acyl group reactions. The final chapters explore the strain energy modeling of simple and crowded aliphatic ketones. These chapters also look into the stereochemistry of dissolving metal reduction of ketones and the hydrolysis of phosphate esters. This book will be of value to physical chemists and physical chemistry researchers and students. |
二甲基亚砜 - 搜狗百科
Jun 17, 2024 · 二甲基亚砜(dmso)是一种含硫有机化合物,常温下为无色无臭的透明液体,是一种吸湿性的可燃液体。 具有高极性、高沸点、热稳定性好、非质子、与水混溶的特性,能溶 …
二甲亚砜(dmso) - 搜狗百科
Jun 17, 2024 · 二甲基亚砜(dmso)是一种含硫有机化合物,分子式为c2h6os,常温下为无色无臭的透明液体,是一种吸湿性的可燃液体。 熔点为18.45℃、沸点为189℃,非质子、与水混溶 …
五月天 - 搜狗百科
May 11, 2024 · 五月天(Mayday),是1997年3月29日成立的中国台湾摇滚乐团,由温尚翊(怪兽)、陈信宏(阿信)、石锦航(石头)、蔡升晏(玛莎)、刘谚明(冠佑)五名成员组成。 …
山奈酚 - 搜狗百科
Sep 27, 2024 · 山奈酚(kaempferol)又名百蕊草素Ⅲ,属于黄酮类化合物,分子结构式为C15H10O6,相对分子量为286.23,其单体纯品为黄色结晶状粉末,熔点276-278℃,微溶于 …
多聚甲醛 - 搜狗百科
Sep 27, 2024 · 多聚甲醛(分子式ho-(ch2o)n-h,其中n为聚合度,n值范围8~100),又称聚合甲醛、聚缩醛、固体甲醛,是一种有甲醛气味的白色无定型颗粒或粉末,是甲醛的线形聚合物。 …
无忧渡 - 搜狗百科
Apr 25, 2025 · 无忧渡 - 搜狗百科
四氯化碳 - 搜狗百科
Dec 5, 2024 · 四氯化碳(carbon tetrachloride),有机化合物,化学式CCl4,是一种无色有毒液体,能溶解脂肪、油漆等多种物质,易挥发液体,具氯仿的微甜气味。 四氯化碳与水互不相 …
朱媛媛 - 搜狗百科
May 27, 2025 · 朱媛媛 - 搜狗百科
硝化棉 - 搜狗百科
Dec 5, 2024 · 硝化棉(Nitrocellulose),别名硝化纤维,是纤维素与硝酸酯化反应的产物,化学式为(C6H7N3O11)n,白色或微黄色棉絮状的硝酸酯类。 不溶于水,能溶于酯、丙酮等有机溶 …
周幽王 - 搜狗百科
Sep 27, 2024 · 周幽王(公元前795年-公元前771年),姬姓,名宫湦(音shēng,一作宫生 ),周宣王姬静之子,母姜后,西周第十二任君主,前782年-前771年在位。姬宫湦死后,谥 …
二甲基亚砜 - 搜狗百科
Jun 17, 2024 · 二甲基亚砜(dmso)是一种含硫有机化合物,常温下为无色无臭的透明液体,是一种吸湿性的可燃液体。 具有高极性、高沸点、热稳定性好、非质子、与水混溶的特性,能溶 …
二甲亚砜(dmso) - 搜狗百科
Jun 17, 2024 · 二甲基亚砜(dmso)是一种含硫有机化合物,分子式为c2h6os,常温下为无色无臭的透明液体,是一种吸湿性的可燃液体。 熔点为18.45℃、沸点为189℃,非质子、与水混溶 …
五月天 - 搜狗百科
May 11, 2024 · 五月天(Mayday),是1997年3月29日成立的中国台湾摇滚乐团,由温尚翊(怪兽)、陈信宏(阿信)、石锦航(石头)、蔡升晏(玛莎)、刘谚明(冠佑)五名成员组成。 …
山奈酚 - 搜狗百科
Sep 27, 2024 · 山奈酚(kaempferol)又名百蕊草素Ⅲ,属于黄酮类化合物,分子结构式为C15H10O6,相对分子量为286.23,其单体纯品为黄色结晶状粉末,熔点276-278℃,微溶于 …
多聚甲醛 - 搜狗百科
Sep 27, 2024 · 多聚甲醛(分子式ho-(ch2o)n-h,其中n为聚合度,n值范围8~100),又称聚合甲醛、聚缩醛、固体甲醛,是一种有甲醛气味的白色无定型颗粒或粉末,是甲醛的线形聚合物。 …
无忧渡 - 搜狗百科
Apr 25, 2025 · 无忧渡 - 搜狗百科
四氯化碳 - 搜狗百科
Dec 5, 2024 · 四氯化碳(carbon tetrachloride),有机化合物,化学式CCl4,是一种无色有毒液体,能溶解脂肪、油漆等多种物质,易挥发液体,具氯仿的微甜气味。 四氯化碳与水互不相 …
朱媛媛 - 搜狗百科
May 27, 2025 · 朱媛媛 - 搜狗百科
硝化棉 - 搜狗百科
Dec 5, 2024 · 硝化棉(Nitrocellulose),别名硝化纤维,是纤维素与硝酸酯化反应的产物,化学式为(C6H7N3O11)n,白色或微黄色棉絮状的硝酸酯类。 不溶于水,能溶于酯、丙酮等有机溶 …
周幽王 - 搜狗百科
Sep 27, 2024 · 周幽王(公元前795年-公元前771年),姬姓,名宫湦(音shēng,一作宫生 ),周宣王姬静之子,母姜后,西周第十二任君主,前782年-前771年在位。姬宫湦死后,谥 …